Two‐Dimensional Metal–Organic Frameworks‐Based Electrocatalysts for Oxygen Evolution and Oxygen Reduction Reactions
Two‐Dimensional Metal–Organic Frameworks‐Based Electrocatalysts for Oxygen Evolution and Oxygen Reduction Reactions
复制标题
DOI：
10.1002/aesr.202000067
复制
发表时间：
2020-12
期刊：
影响因子：
--
通讯作者：
Qiang-long Qi;Jue Hu;Yingjie Zhang;Wei Li;Bolong Huang;Chengxu Zhang
中科院分区：
文献类型：
--
作者：
Qiang-long Qi;Jue Hu;Yingjie Zhang;Wei Li;Bolong Huang;Chengxu Zhang
由于其独特的内在性质和灵活的结构调制，二维金属有机框架（mof）基材料已成为析氧反应（OER）和氧还原反应（ORR）等能量转换系统中最有前途的电催化剂。本文首先介绍了二维MOF基电催化剂的研究背景，并根据OER和ORR对二维MOF基电催化剂进行了分类。同时，重点讨论了基于MOF的二维OER和ORR电催化剂的最新进展，包括精细的合成策略、新颖的结构、独特的形貌、优异的电催化性能和潜在的反应机理。最后，对基于mof的二维OER和ORR电催化剂的发展和研究提出了挑战和未来的展望。
Due to unique intrinsic properties and flexible structure modulations, 2D metal–organic frameworks (MOFs)‐based materials have become the most promising candidates in the electrocatalysts of energy‐conversion systems such as oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). Herein, the background of fundamental 2D MOFs is first introduced and 2D MOF‐based electrocatalysts are classified based on OER and ORR. Meanwhile, the recent advances in the 2D MOF‐based OER and ORR electrocatalysts are emphasized and discussed including the subtle synthesis strategy, novel structures, unique morphologies, superior electrocatalytic performances, and the underlying reaction mechanism. Finally, the challenges and future perspectives for the developments and research of 2D MOFs‐based OER and ORR electrocatalysts are proposed.