Functional group compatible palladium-catalyzed cross-coupling reactions between aryllithium and aryl halide mediated by a five-membered cyclic silyl ether
Functional group compatible palladium-catalyzed cross-coupling reactions between aryllithium and aryl halide mediated by a five-membered cyclic silyl ether
复制标题
DOI：
10.1246/bcsj.79.492
复制
发表时间：
2006-03-15
影响因子：
4
通讯作者：
Tamao, K
中科院分区：
文献类型：
--
作者：
Son, EC;Tsuji, H;Tamao, K
以五元环硅烷为前驱体，发展了钯催化的芳基锂与芳基卤化物的交叉偶联反应。该反应在温和的条件下进行，不需要添加氟化盐或碱来激活硅基试剂。
A functional group compatible palladium-catalyzed cross-coupling reaction between aryllithiums and aryl halides mediated by a five-membered cyclic silyl ether as a precursor for an activated arylsilane has been developed. The reaction proceeds under mild conditions without the addition of a fluoride salt or a base to activate the silyl reagent.