Probing borafluorene B–C bond insertion with gold acetylide and azide
Probing borafluorene B–C bond insertion with gold acetylide and azide
复制标题
用乙炔金和叠氮化物探测硼芴 B−C 键插入
DOI：
10.1039/d2dt03672j
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发表时间：
2023
影响因子：
4
通讯作者：
Martin, Caleb D.
中科院分区：
文献类型：
--
作者：
Li, Yijie;Shen, Yu-Hsuan;Esper, Alec M.;Tidwell, John R.;Veige, Adam S.;Martin, Caleb D.
Ph3PAuN3 与 9-Ph-9-硼芴的反应导致叠氮化物与硼络合，而乙炔金与 9-Ph-9-硼芴反应插入乙炔碳，形成具有环外双键的六元硼环。
The reaction of Ph3PAuN3 with 9-Ph-9-borafluorene resulted in complexation of the azide to boron while a gold acetylide reacted with 9-Ph-9-borafluorene to insert the acetylide carbon to access a six-membered boracycle with an exocyclic double bond.