Synthesis and electrochemical properties of Fe3O4/MnO2/RGOs sandwich-like nano-superstructures

Synthesis and electrochemical properties of Fe3O4/MnO2/RGOs sandwich-like nano-superstructures
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Fe3O4/MnO2/RGOs三明治状纳米超结构的合成及电化学性能

DOI:
10.1016/j.jallcom.2016.09.156
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发表时间:
2017-02-05
影响因子:
6.2
通讯作者:
Xu, Hongwu
Xu, Hongwu
中科院分区:
材料科学2区
文献类型:
--
作者:
Li, Jing;Chen, Yun;Xu, Hongwu

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The Fe3O4/MnO2/RGOs (Reduced graphene oxide) sandwich-like nano-superstructures reported in this article were fabricated by using an eco-friendly mechanical stirring route at room temperature without any catalysts or templates. In this nano-superstructure, three-dimensional (3D) hierarchical MnO2 shell was assembled by two-dimensional (2D) nanoplates and Fe3O4/MnO2 core-shell was coated by RGO layers. The sandwich-like nano-superstructures show better electrochemical performance comparing to the pure MnO2 and Fe3O4/MnO2 nanoparticles. The maximum specific capacitance can reach 77.5 F/g at the current density of 0.5 A/g and maintain 35.0 F/g (55% of SC at 0.5 A/g) at the current density of 20 A/g. It was found that the electrocapacitive performances of the Fe3O4/MnO2/RGO electrodes are highly affected by the connection effectiveness between Fe3O4/MnO2 particles and graphene layers. (C) 2016 Elsevier B.V. All rights reserved.