Selective Hydrogenation of 9-Aminoacridine over Supported Noble Metal Catalysts
Selective Hydrogenation of 9-Aminoacridine over Supported Noble Metal Catalysts
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负载型贵金属催化剂上 9-氨基吖啶的选择性加氢
DOI：
10.1246/cl.1990.319
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发表时间：
1990
影响因子：
1.6
通讯作者：
M. Soeda
中科院分区：
文献类型：
--
作者：
K. Sakanishi;I. Mochida;H. Okazaki;M. Soeda
研究了贵金属催化剂(Pd、Rh、Pt和Ru)在80℃和60℃左右的氢气气氛下，9-氨基吖啶(1)选择加氢合成1，2，3，4-四氢衍生物(2)的反应。Pd/Al_2O_3催化剂选择性最高，转化率为97%，产率为60%。讨论了1的氢化途径，并与吖啶的氢化途径进行了比较。
The selective hydrogenation of 9-aminoacridine(1) into 1,2,3,4-tetrahydro-derivative(2) was searched using noble metal catalysts(Pd, Rh, Pt, and Ru) at around 80 °C and 60 °C atm of H2. The Pd/Al2O3 catalyst was found most selective to produce 2 in a higher yield of 60% at a conversion of 97%. The hydrogenation pathway of 1 is discussed in comparison with that of acridine.