Preparation of inclusion complexes between amylose and ester-containing polymers by means of vine-twining polymerization
Preparation of inclusion complexes between amylose and ester-containing polymers by means of vine-twining polymerization
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DOI：
10.1002/macp.200350004
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发表时间：
2003-07-25
影响因子：
2.5
通讯作者：
Tagaya, H
中科院分区：
文献类型：
--
作者：
Kadokawa, J;Nakaya, A;Tagaya, H
本文报道了用酶法聚合α-D-葡萄糖-1-磷酸单体(GLC-1-P)制备直链淀粉与合成聚合物的包合物。作为客体的合成聚合物是主链上含有酯基的聚己内酯、聚戊内酯和聚酯醚。包合物的形成是在客体聚合物存在下，由磷酸酶催化的GLC-1-P的聚合反应。
This paper reports the preparation of inclusion complexes of amylose with synthetic polymers by means of enzymatic polymerization of alpha-D-glucose 1-phosphate monomer (Glc-1-P). The synthetic polymers, employed as the guests, are poly(epsilon-caprolactone), poly(delta-valerolactone), and poly(ester-ether), containing ester groups in the main chains The formation of the inclusion complexes was carried out by the enzymatic polymerization of Glc-1-P catalyzed by phosphorylase in the presence of the guest polymers.