Absolute kinetics of mesitylmethylchlorocarbene reactions
Absolute kinetics of mesitylmethylchlorocarbene reactions
复制标题
异亚丙基甲基氯卡宾反应的绝对动力学
DOI：
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发表时间：
1997
期刊：
影响因子：
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通讯作者：
D. C. Merrer
中科院分区：
文献类型：
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作者：
R. Moss;D. C. Merrer
测定了反应的绝对速率常数
Absolute rate constants were determined for reactions of
mesitylmethylchlorocarbene, which affords intramolecular products derived
from 1,2-H migration, 1,2-mesityl migration, and C–H insertion; at
-35 or -70 °C, however, the intrusion of intermolecular
channels affords azine and carbene dimer, complicating interpretations of
the kin-etics.