Synthesis, characterization, and photophysical properties of bismetalated platinum complexes with benzothiophene ligands
Synthesis, characterization, and photophysical properties of bismetalated platinum complexes with benzothiophene ligands
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DOI：
10.1016/j.jorganchem.2018.12.010
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发表时间：
2019-03-01
影响因子：
2.3
通讯作者：
Tanski, Joseph M.
中科院分区：
文献类型：
--
作者：
Anderson, Craig M.;Mastrocinque, Claudio;Tanski, Joseph M.
通过Suzuki偶联反应合成了含有喹啉或吡啶基团的苯并噻吩基配体，随后与双核铂化合物[Pt2Me4 (mu-SMe2)(2)]、PtA反应，研究螯合物辅助C-H活化。报道了CN环金属化产物的制备和表征，包括eta(2)中间体、单金属化和双金属化产物。研究了配合物的光物理性质，并与TD-DFT计算结果进行了比较。(C) 2018年Elsevier B.V.出版
Benzothiophene-based ligands containing quinoline or pyridine moieties were synthesized through Suzuki Coupling reactions and subsequently reacted with the binuclear Platinum compound, [Pt2Me4 (mu-SMe2)(2)], PtA, in order to study chelate-assisted C-H activation. The preparation and characterization of CN cyclometalated products, including eta(2) intermediates, monometalated, and bismetalated species, are reported. The photophysical properties of the complexes were studied and compared to TD-DFT computational results. (C) 2018 Published by Elsevier B.V.