M.C.D./M.C.P.L. saturation theory with application to molecules in D ∞h and its subgroups
M.C.D./M.C.P.L. saturation theory with application to molecules in D ∞h and its subgroups
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M.C.D./M.C.P.L. 饱和理论及其在 D ∞h 及其子群中的应用
DOI：
10.1080/00268977800101151
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发表时间：
1978
影响因子：
1.7
通讯作者：
E. Krausz
中科院分区：
文献类型：
--
作者：
P. Schatz;R. Mowery;E. Krausz
医学中心在足够高的磁场和/或足够低的温度下，具有顺磁基态的系统的H/T将偏离简单的H/T依赖性，并且这种偏离被称为饱和效应。详细的理论讨论这一现象，并具体应用于点群D ∞h和在其子群下通过C3的分子。一个单一的一般公式被发现适用于在所有情况下，允许电子过渡之间的两个“孤立”的电子状态。文中较详细地介绍了该公式的性质和应用。然后将该公式推广到适用于相应的发射现象，磁圆偏振发光（M.C.P.L.），其中必须考虑光选择的附加效应。M.C.D.中的饱和度分析还提出了一个特殊的情况下，意外简并，即为2 P 3/2的“原子”基态的线性分子。在萨图尔的各种实验考虑.
The M.C.D. of a system with a paramagnetic ground state will deviate from simple H/T dependence at sufficiently high field and/or low temperature, and this deviation is referred to as a saturation effect. A detailed theoretical discussion of this phenomenon is presented, and specific application is made to molecules in point group D ∞h and in its subgroups down through C 3. A single general formula is found to apply in all cases to an allowed electronic transition between two ‘isolated’ electronic states. The properties and applications of this formula are described in some detail. The formula is then generalized to apply to saturation behaviour for the corresponding emission phenomenon, magnetic circularly polarized luminescence (M.C.P.L.), where the additional effect of photoselection must be considered. A saturation analysis in M.C.D. is also presented for one special case of accidental degeneracy, that for a 2P3/2 ‘atomic’ ground state in a linear molecule. Various experimental considerations in satur...