A new family of cation-binding compounds: threo-.alpha.,.omega.-poly(cyclooxalkane)diyl
A new family of cation-binding compounds: threo-.alpha.,.omega.-poly(cyclooxalkane)diyl
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阳离子结合化合物的新家族：苏型-.α.,.omega.-聚(环氧烷)二基
DOI：
10.1021/ja00547a049
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发表时间：
1980
影响因子：
15
通讯作者：
Samuel M. Smith
中科院分区：
文献类型：
--
作者：
W. J. Schultz;M. C. Etter;A. V. Pocius;Samuel M. Smith
这些聚合物中的某些以类似于冠醚的方式结合阳离子。然而，与络合能力在很大程度上由相对阳离子和大环空腔尺寸决定的冠醚不同，1-3给定的化合物可以有效地结合各种尺寸的阳离子，例如Li+、Ba 2+和亚甲基蓝。1的阳离子结合性质是部分的，
Certain of these polymers bind cations in a manner similar to that of the crown ethers. However, unlike the crowns, whose complexing ability is determined to a large extent by the relative cation and macrocycle cavity dimensions, 1-3 a given 1 compound can effectively bind cations of widely varying sizes, eg, Li+, Ba2+, and methylene blue. Cation binding properties of 1 are partic-