The Quest for Chain-Link Hydrogen-Bonded Capsules: Self-Assembly of C-Methyl Calix[4]resorcinarene with 1,2-Bis(5‘-pyrimidyl)ethyne
The Quest for Chain-Link Hydrogen-Bonded Capsules: Self-Assembly of C-Methyl Calix[4]resorcinarene with 1,2-Bis(5‘-pyrimidyl)ethyne
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DOI：
10.1021/cg034108c
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发表时间：
2004-01
影响因子：
3.8
通讯作者：
Ivan Georgiev and;E. Bosch;C. Barnes;M. Draganjac
中科院分区：
文献类型：
--
作者：
Ivan Georgiev and;E. Bosch;C. Barnes;M. Draganjac
报道了四齿配体1,2-二（5′-嘧啶基）乙炔与c -甲基杯[4]间苯二甲酸在多种条件下的自组装。介绍了自组装形成的两种不同的三维氢键网络的结构。一种结构包含配体桥接的间苯二甲酸脂，具有“链式”胶囊基序。另一种结构是交联堆叠间苯二甲酸酯的三维网络。
The self-assembly of the tetradentate ligand 1,2-bis(5‘-pyrimidyl)ethyne with C-methyl calix[4]resorcinarene under a variety of conditions is reported. The structures of two different three-dimensional hydrogen bonded networks formed on self-assembly are presented. One structure contains ligand-bridged resorcinarenes with a “chain-link” capsule motif. The other structure is a three-dimensional network of cross-linked stacked resorcinarenes.