Facile conversion of spirostan saponin into furostan saponin: synthesis of methyl protodioscin and its 26-thio-analogue.
Facile conversion of spirostan saponin into furostan saponin: synthesis of methyl protodioscin and its 26-thio-analogue.
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DOI：
10.1021/ol060594w
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发表时间：
2006-05
期刊：
影响因子：
5.2
通讯作者：
Ming Li;Biao Yu
中科院分区：
文献类型：
--
作者：
Ming Li;Biao Yu
[反应：已经开发了一种将螺甾烷皂苷转化为其呋甾烷对应物的简便方法，如薯蓣皂苷转化为甲基原薯蓣皂苷（及其26-硫代类似物）所示。
[reaction: see text] A facile approach for the conversion of a spirostan saponin into its furostan counterpart, as illustrated by the transformation of dioscin to methyl protodioscin (and its 26-thio-analogue), has been developed.