Adsorption-induced deformation of AUK microporous carbon adsorbent in adsorption of n-pentane
Adsorption-induced deformation of AUK microporous carbon adsorbent in adsorption of n-pentane
复制标题
AUK微孔碳吸附剂吸附正戊烷时的吸附变形
DOI：
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发表时间：
2011
期刊：
影响因子：
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通讯作者：
V. Sinitsyn
中科院分区：
文献类型：
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作者：
A. Shkolin;A. Fomkin;V. Sinitsyn
在1 Pa ~ 50 kPa的压力范围和243、273、293、313、353、393 K的温度条件下，测量了AUK微孔碳吸附剂在正戊烷吸附过程中的相对线性吸附变形等温线。在整个温度范围内，吸附变形曲线具有相似的行为。除初始压力范围p < 400pa外，吸附变形随压力增大而增大，随温度升高而减小。当压力小于400pa时，吸附变形的影响表现得非常弱。然而，在此压力范围内，在低于350 K的温度下，吸附剂的初始压缩（0.01%）被观察到，随着温度的降低，其增加。在较高的温度下，观察到吸附剂急剧膨胀0.002%，这使它们转移到一个狭窄的变形恒定区域。在此范围之外，吸附剂在所有温度范围内随着压力的增加而膨胀。
The isotherms of the relative linear adsorption deformation of AUK microporous carbon adsorbent are measured during the n-pentane adsorption within the pressure range of 1 Pa to 50 kPa and at temperatures of 243, 273, 293, 313, 353, and 393 K. The curves of adsorption deformation have similar behavior within the whole range of investigated temperatures. Except for the initial pressure range p < 400 Pa, the adsorption deformation increases as pressure grows and reduces as temperature grows. The effects of adsorption deformation manifest extremely weakly at pressures of less than 400 Pa. Nevertheless, in this pressure range, at temperatures below 350 K, the initial compression of adsorbent (0.01%) is observed, which increases as temperature reduces. At higher temperatures, the sharp initial adsorbent expansion by 0.002% is observed, which transfers them to a narrow region of deformation constancy. Beyond this region, the adsorbent expands in all temperature ranges as the pressure increases.