BIOSYNTHESIS OF GRAMINE - FEEDING EXPERIMENTS WITH TRYPTOPHAN-BETA-[H3,C14]

BIOSYNTHESIS OF GRAMINE - FEEDING EXPERIMENTS WITH TRYPTOPHAN-BETA-[H3,C14]
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DOI:
10.1021/ja00887a021
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发表时间:
1963-01-01
影响因子:
15
通讯作者:
LEETE, E
LEETE, E
中科院分区:
化学1区
文献类型:
--
作者:
ODONOVAN, D;LEETE, E

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分别标记(C14和H3)的混合物的麦烷喂给大麦幼苗和所得的标记分离的禾本科。禾本科植物中的C14与H3的比率与进料的禾本科植物中的比率相同。这表明,亚甲基基团没有改变的过程中的藜芦烷到芦竹碱的转化。
Separately labelled (C14 and H3) mixtures of tryptophane were fed to barley seedlings and the resulting labelled gramine isolated. The C14 to H3 ratio in the gramine was the same as the ratio in the tryptophane fed. This suggest that the methylene group is not changed during the conversion of the tryptophane to gramine.