Hydrogen and CO2 Reduction Reactions: Mechanisms and Catalysts

Hydrogen and CO2 Reduction Reactions: Mechanisms and Catalysts
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DOI:
10.1007/978-3-319-29641-8_3
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发表时间:
2016
期刊:
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影响因子:
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通讯作者:
P. Sudhagar;Nitish Roy;R. Vedarajan;A. Devadoss;C. Terashima;K. Nakata;A. Fujishima
P. Sudhagar;Nitish Roy;R. Vedarajan;A. Devadoss;C. Terashima;K. Nakata;A. Fujishima
中科院分区:
其他
文献类型:
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作者:
P. Sudhagar;Nitish Roy;R. Vedarajan;A. Devadoss;C. Terashima;K. Nakata;A. Fujishima

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电催化还原水通过析氢反应或CO2还原为有用的燃料可能为未来提供可持续的能源供应。在本章中,我们讨论了最新的发展,电催化材料的析氢(H2)反应和二氧化碳(CO2)的还原,已实施的电化学或光电化学反应。在此专门概述了考虑到管理成本和材料可用性,用地球丰富的半导体材料替代昂贵的铂催化剂的新兴策略。此外,本章展示了新材料,涂料和他们最近的进步,以实现高效率的太阳能燃料转换从水和其他污染物。总之,本章提供了一个全面的框架,对广泛的材料,催化剂(析氢电催化剂和光催化剂)和蚀刻洞察催化的基本原理和起源之间的一致和有意义的比较。
The electrocatalytic reduction of water to useful fuel via the hydrogen evolution reaction or CO2reduction may afford a sustainable energy supply for the future. In this chapter, we discuss the recent developments on electrocatalytic materials for hydrogen (H2) evolution reaction and carbon dioxide (CO2) reduction which have been implemented in photocatalysis or photoelectrochemical reactions. The emerging strategies for replacing expensive platinum catalyst with earth abundant semiconductor materials in view of managing cost and material availability has been exclusively outlined here. Also, this chapter showcases novel materials, coatings and their recent strides to achieve high efficiency solar to fuel conversion from water and other pollutants. In summary, this chapter provides a holistic framework on a wide spectrum of materials, with consistent and meaningful comparisons between catalysts (hydrogen evolution electrocatalyst and photocatalyst) and etching insight into fundamentals and origin of catalysis.