Bis(stibahousene).
Bis(stibahousene).
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双（stibahousene）。
DOI：
10.1021/jacs.7b07712
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发表时间：
2017
影响因子：
15
通讯作者：
H. Gornitzka
中科院分区：
文献类型：
--
作者：
V. Ya. Lee;K. Ota;Y. Ito;O. A. Gapurenko;A. Sekiguchi;R. M. Minyaev;V. I. Minkin;H. Gornitzka
应变碳氢化合物是有机化合物中最重要的一类。其中，双环[2.1.0]戊烯（“housene”）衍生物是一个极具挑战性和极具吸引力的类别。虽然有机温室已经被发现了50多年，但仍然很少有有机温室含有较重的主族元素。本文报道了两种house型结构，新型单体stibahousene和二聚体bis（stibahousene）。从实验和计算两方面探讨了这两种化合物的成键性质，揭示了它们独特的结构特征。
Strained hydrocarbons constitute one of the most prominent classes of organic compounds. Among them, bicyclo[2.1.0]pentene (“housene”) derivatives represent a highly challenging and very attractive class. Although organic housenes have been known for more than five decades, there are still very few of them containing heavier main group elements. In this paper, we report on the two housene-type structures, novel monomeric stibahousene and dimeric bis(stibahousene). The bonding natures of both compounds were approached from both experimental and computational directions to reveal their peculiar structural features.