The emergence of zerovalent carbon compounds from structural curiosities to organocatalysts
The emergence of zerovalent carbon compounds from structural curiosities to organocatalysts
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DOI：
10.1016/j.xcrp.2023.101519
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发表时间：
2023-07
影响因子：
8.9
通讯作者：
Allegra L. Liberman-Martin
中科院分区：
文献类型：
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作者：
Allegra L. Liberman-Martin
低价主族化合物具有过渡金属的反应性模式和性质。虽然二价碳化合物，如卡宾，是被广泛研究的配体和有机催化剂，但零价碳物种得到的关注却相当少。这一观点强调了零价碳化合物的性质和反应活性，重点放在它们作为小分子还原和聚合反应的有机催化剂的第一次应用。
Low-valent main group compounds have reactivity patterns and properties reminiscent of transition metals. While divalent carbon compounds such as carbenes are widely studied ligands and organocatalysts, zerovalent carbon species have received considerably less attention. This perspective highlights the properties and reactivity of zerovalent carbon compounds, focusing on their first applications as organocatalysts for small molecule reduction and polymerization reactions.