Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes
Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes
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DOI：
10.1039/d0cc03541f
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发表时间：
2020-11-07
影响因子：
4.9
通讯作者：
Iguchi, Hiroaki
中科院分区：
文献类型：
--
作者：
Koyama, Shohei;Tanabe, Tappei;Iguchi, Hiroaki
采用萘二亚胺（NDI）基有机配体的初步化学还原法制备了具有中性金属节点（乙酰丙酮钴）的多孔分子导体（PMC）。所获得的半导体PMC （PMC-2）是稳定的，由于中性金属节点，提供了优于电化学还原。
Preliminary chemical reduction of naphthalenediimide (NDI)-based organic ligands was applied to the synthesis of a porous molecular conductor (PMC) with neutral metal nodes (cobalt(ii) acetylacetonate). The obtained semiconductive PMC (PMC-2) was stable due to the neutral metal nodes, providing an advantage over electrochemical reduction.