Isolation of the elusive [Ru(bipy) 3 ] + : a key intermediate in photoredox catalysis
Isolation of the elusive [Ru(bipy) 3 ] + : a key intermediate in photoredox catalysis
复制标题
难以捉摸的 [Ru(bipy) 3 ] 的分离：光氧化还原催化中的关键中间体
DOI：
10.1039/d3cc04375d
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发表时间：
2023
影响因子：
4.9
通讯作者：
Scott, Daniel J.
中科院分区：
文献类型：
--
作者：
Horsewill, Samuel J.;Cao, Chengyang;Dabney, Noah;Yang, Eric S.;Faulkner, Stephen;Scott, Daniel J.
近年来，光氧化还原催化蓬勃发展，但由于其广泛的实用性，应用增长速度超过了机械理解。在这份报告中，我们帮助解决这个赤字的隔离和表征的标志性的光催化剂[Ru（bipy）3]2+的中间体之一，并测试其对常见的基板的初始光反应性。
Photoredox catalysis has flourished in recent years, but due to its widespread utility applications have grown faster than mechanistic understanding. In this report we help to address this deficit by isolating and characterising one of the intermediates of the iconic photocatalyst [Ru(bipy)3]2+, and testing its initial photoreactivity towards common substrates.