The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reaction via a proposed Ni(III) NCP intermediate.
The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reaction via a proposed Ni(III) NCP intermediate.
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DOI：
10.1039/b904615a
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发表时间：
2009-06
影响因子：
4.9
通讯作者：
Hua-Wei Jiang;Qing‐Yun Chen;Ji-Chang Xiao;Yucheng Gu
中科院分区：
文献类型：
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作者：
Hua-Wei Jiang;Qing‐Yun Chen;Ji-Chang Xiao;Yucheng Gu
用偶氮自由基引发剂氧化Ni（II）N-混乱卟啉（NCPs），通过Ni（III）NCP中间体发生了一个意想不到的分子内亲核取代反应，该反应可以用高分辨质谱（HRMS）检测到.
The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators resulted in an unexpected intramolecular nucleophilic substitution reaction via a proposed Ni(III) NCP intermediate, which could be detected by HRMS.