One-pot synthesis of a novel tridentate tin(IV) ligand; syntheses and structures of [BunSn(NC5H4-C,N)3MBr](M = Li, Cu)

One-pot synthesis of a novel tridentate tin(IV) ligand; syntheses and structures of [BunSn(NC5H4-C,N)3MBr](M = Li, Cu)
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新型三齿锡(IV)配体的一锅法合成;

DOI:
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发表时间:
1996
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通讯作者:
D. Wright
D. Wright
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文献类型:
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作者:
Michael A. Beswick;C. Belle;M. Davies;M. Halcrow;P. Raithby;A. Steiner;D. Wright

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在[Sn(C5 H5)2]与2-锂硫代吡啶反应过程中,[BunBr]副产物进一步反应生成[BunSn(NC 5 H4-C,N)3LiBr]·0.5thf 1,其配体与CuCl 2作用生成[BunSn(NC 5 H4-C,N)3CuBr]·0.5thf 2
During the reaction of [Sn(C5H5)2] with 2-lithiopyridine, further reaction of the [BunBr] byproduct leads to the formation of [BunSn(NC5H4-C,N)3LiBr]·0.5thf 1, interaction of the tris(pyridyl)tin(IV) ligand of which, with CuCl2, produces [BunSn(NC5H4-C,N)3CuBr]·0.5thf 2