An Olefin Metathesis/Double Bond Isomerization Sequence Catalyzed by an In Situ Generated Ruthenium Hydride Species
An Olefin Metathesis/Double Bond Isomerization Sequence Catalyzed by an In Situ Generated Ruthenium Hydride Species
复制标题
原位生成的氢化钌物质催化的烯烃复分解/双键异构化序列
DOI：
10.1002/ejoc.200390124
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发表时间：
2003
影响因子：
2.8
通讯作者：
B. Schmidt
中科院分区：
文献类型：
--
作者：
B. Schmidt
描述了使用烯烃复分解/双键迁移序列将烯丙基醚直接转化为环状烯醇醚。钌卡宾络合物通过添加氢化物源（例如NaH或NaBH 4）活化以催化双键迁移步骤。（© Wiley-VCH Verlag GmbH & Co. KGaA，69451魏因海姆，德国，2003）
The direct conversion of allyl ethers to cyclic enol ethers using an olefin metathesis/double bond migration sequence is described. Ruthenium carbene complexes were activated to catalyze the double bond migration step by addition of hydride sources, such as NaH or NaBH4. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)