Oxygenophilic Ionic Liquids Promote the Oxygen Reduction Reaction in Pt-Free Carbon Electrocatalysts
Oxygenophilic Ionic Liquids Promote the Oxygen Reduction Reaction in Pt-Free Carbon Electrocatalysts
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DOI:
10.1039/c7mh00298j
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发表时间:
2017-08
影响因子:
13.3
通讯作者:
Mo Qiao;Cheng Tang;L. Tănase;C. Teodorescu;Chengmeng Chen;Qiang Zhang;M. Titirici
中科院分区:
文献类型:
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作者:
Mo Qiao;Cheng Tang;L. Tănase;C. Teodorescu;Chengmeng Chen;Qiang Zhang;M. Titirici
We propose a novel idea to improve the surface properties of carbon-based Pt-free electrocatalysts in Polymer Electrolyte Membranes (PEMs) and Alkaline Fuel Cells (AFCs). Our concept is based on the addition of oxygenophilic and hydrophobic ionic liquids (ILs) to form a thin passivating layer at the triple point between the electrocatalyst–electrolyte–gas interface where the Oxygen Reduction Reaction (ORR) takes place.