Enclave inclusion of nitromethane by a new crown host. X-Ray crystal structure of the inclusion complex and host selectivity properties

Enclave inclusion of nitromethane by a new crown host. X-Ray crystal structure of the inclusion complex and host selectivity properties
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新冠宿主包含硝基甲烷的飞地。

DOI:
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发表时间:
1986
期刊:
影响因子:
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通讯作者:
J. Ahrendt
J. Ahrendt
中科院分区:
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文献类型:
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作者:
E. Weber;S. Franken;H. Puff;J. Ahrendt

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一个21元的标记(1)包含一个2,6桥联吡啶位点和三个相邻的儿茶酚基团作为特征构建块,显示出与硝基甲烷选择性地形成包合物,其晶体结构显示出完全封装的客体分子。
A 21-membered macroring (1) incorporating as characteristic building blocks a 2,6-bridged pyridino site and three adjacent catechol moieties is shown to form selectively an inclusion complex with nitromethane, the crystal structure of which demonstrates a completely encapsulated guest molecule.