Molecular Doping of Porous Organic Cages
Molecular Doping of Porous Organic Cages
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DOI：
10.1021/ja205969q
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发表时间：
2011-09-28
影响因子：
15
通讯作者：
Cooper, Andrew I.
中科院分区：
文献类型：
--
作者：
Hasell, Tom;Schmidtmann, Marc;Cooper, Andrew I.
多孔有机笼可以作为主体的三维对齐的客人，如卤素和有机金属。通过气相升华掺杂多孔单晶以产生客体如I-5（-）和OsO 4的金刚石状排列，导致I-5（-）的情况下显著的导电性增强。
Porous organic cages can act as hosts for the three-dimensional alignment of guests such as halogens and organometallics. Porous single crystals are doped by vapor sublimation to produce diamondoid arrangements of guests such as I-5(-) and OsO4, leading to marked conductivity enhancement in the case of I-5(-).