Covalent Organic Frameworks as Electrode Materials for Rechargeable Batteries
Covalent Organic Frameworks as Electrode Materials for Rechargeable Batteries
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DOI：
10.1055/s-0041-1723020
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发表时间：
2021-01
影响因子：
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通讯作者：
Eric R. Wolfson;Erica M. Moscarello;W. K. Haug;Psaras L. McGrier
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文献类型：
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作者：
Eric R. Wolfson;Erica M. Moscarello;W. K. Haug;Psaras L. McGrier
共价有机框架（COFs）是一类先进的晶体多孔聚合物，由于其可调的性质和强大的分子结构而引起了人们的极大兴趣。因此，具有储能性能的COFs是可充电电池电极材料领域特别感兴趣的材料。然而，对COFs作为储能材料候选者的研究仍处于起步阶段。本文将重点介绍用于制造用作电极材料的COFs的方法，并讨论对其生产至关重要的因素。将介绍一系列已知的基于cof的储能系统。此外，在传统锂离子电池之外的系统中利用COFs的存储特性的能力也将得到解决。展望将阐述该领域目前的进展和面临的挑战，最终扩大其应用范围。
Abstract Covalent organic frameworks (COFs) are an advanced class of crystalline porous polymers that have garnered significant interest due to their tunable properties and robust molecular architectures. As a result, COFs with energy-storage properties are of particular interest to the field of rechargeable battery electrode materials. However, investigation into COFs as candidates for energy-storage materials is still in its infancy. This review will highlight methods used to fabricate COFs used as electrode materials and discuss the factors that prove critical for their production. A collection of known COF-based energy-storage systems will be featured. In addition, the ability to utilize the storage properties of COFs for systems beyond traditional Li-ion batteries will be addressed. An outlook will address the current progress and remaining challenges facing the field to ultimately expand the scope of their applications.