Synergistic Effect between a Novel Hyperbranched Flame Retardant and Melamine Pyrophosphate on the Char Forming of Polyamide 6

Synergistic Effect between a Novel Hyperbranched Flame Retardant and Melamine Pyrophosphate on the Char Forming of Polyamide 6
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新型超支化阻燃剂与三聚氰胺焦磷酸盐对聚酰胺 6 成炭的协同作用

DOI:
10.1080/03602559.2010.512325
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发表时间:
2010-11
影响因子:
--
通讯作者:
Zhu, Jin
Zhu, Jin
中科院分区:
化学3区
文献类型:
--
作者:
Ke, Chenhao;Yan, Qing;Fang, Keyi;Zhu, Qiliang;Li, Juan;Zhu, Jin

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A novel hyperbranched polyphosphate bisphenol-S ester (HPPES) flame retardant was prepared. The structure and thermal stability of the product were characterized. Polyamide 6 (PA6), HPPES and melamine pyrophosphate (MPP) were used to prepare flame retardant PA6 (FR-PA6) through melt blending. Limiting oxygen index (LOI), UL-94 vertical burning methods, thermogravimetric analysis (TGA), X-ray photoelectron spectroscope (XPS) and scanning electron microscope (SEM) were used to investigate the combustion properties, thermal degradation behaviours and char forming of FR-PA6. The results showed that synergistic effect between HPPES and MPP was present, which enhanced the char forming and flame retardance of PA6.
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