Laminar Flame Characteristics and Kinetic Modeling Study of Ethyl Tertiary Butyl Ether Compared with Methyl Tertiary Butyl Ether, Ethanol, iso-Octane, and Gasoline

Laminar Flame Characteristics and Kinetic Modeling Study of Ethyl Tertiary Butyl Ether Compared with Methyl Tertiary Butyl Ether, Ethanol, iso-Octane, and Gasoline
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乙基叔丁基醚与甲基叔丁基醚、乙醇、异辛烷和汽油的层流火焰特性和动力学模型研究

DOI:
10.1021/acs.energyfuels.7b03636
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发表时间:
2018-02
期刊:
影响因子:
5.3
通讯作者:
Zuohua Huang
Zuohua Huang
中科院分区:
工程技术3区
文献类型:
--
作者:
Erjiang Hu;Jinfeng Ku;Geyuan Yin;Chanchan Li;Xin Lu;Zuohua Huang

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在不同的初始温度(298 K、373 K、453 K)和压力(1个大气压、3个大气压、5个大气压)下,在定容燃烧弹中测量了乙基叔丁基醚(ETBE)的层流火焰速度。还针对甲基叔……进行了层流火焰实验。
Laminar flame speeds of ethyl tertiary butyl ether (ETBE) were measured in a constant volume bomb at different initial temperatures (298 K, 373 K, 453 K) and pressures (1 atm, 3 atm, 5 atm). The laminar flame experiments were also conducted for methyl tertiary butyl ether (MTBE), ethanol, iso-octane, and gasoline for the comparison of laminar flame speeds and Markstein lengths. Experimental results show that laminar flame speeds peak at the equivalence ratio of 1.1 for all tested fuels. Ethanol has the fastest laminar flame speed and the other fuels have similar flame speeds, indicating replacing MTBE with ETBE in gasoline will not influence the laminar flame speed of present gasoline. The CRECK and Curran mechanisms were validated by experimental results of ETBE and neither could predict laminar flame speeds well. Curran mechanism was optimized by updating the underlying mechanism, and the Modified Curran mechanism has better prediction performance on the laminar flame speed. Sensitivity analyses were al...
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