Facile synthesis of 2,2′-dinitrosubstituted biaryls through Cu-catalyzed ligand-free decarboxylative homocoupling of ortho-nitrobenzoic acids
Facile synthesis of 2,2′-dinitrosubstituted biaryls through Cu-catalyzed ligand-free decarboxylative homocoupling of ortho-nitrobenzoic acids
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DOI：
10.1039/c5ra07771k
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发表时间：
2015-01-01
期刊：
影响因子：
3.9
通讯作者：
Cai, Hu
中科院分区：
文献类型：
--
作者：
Fu, Zhengjiang;Li, Zhaojie;Cai, Hu
A novel waste-free Cu-catalyzed decarboxylative homocoupling of ortho-nitrobenzoic acids has been developed, and diverse substituents on the phenyl core of ortho-nitrobenzoic acid are compatible with the transformation. This method provides a practical alternative to synthesize valuable 2,2'-dinitrosubstituted biaryls from cheap and readily available ortho-nitrobenzoic acids.
