Alkyl length effects on solid-state fluorescence and mechanochromic behavior of small organic luminophores
Alkyl length effects on solid-state fluorescence and mechanochromic behavior of small organic luminophores
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烷基长度对小型有机发光体的固态荧光和力致变色行为的影响
DOI：
10.1039/c5tc04358a
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发表时间：
2016-02
影响因子：
6.4
通讯作者：
Yang Wenjun
中科院分区：
文献类型：
--
作者：
Xue Shanfeng;Qiu Xu;Sun Qikun;Yang Wenjun
在有机发色团的共轭骨架外围引入烷基链一般是为了提高其溶解性。然而，大量的研究表明，烷基链的长度对固态分子的堆积模式和光电性质有着重要的影响，因此烷基链可以在调节和改变固态聚集行为和光电性质方面发挥功能性作用。虽然已经有各种各样的报道烷基链对有机场效应晶体管和光伏性能的影响，最近越来越多的兴趣已经支付的烷基长度如何影响有机荧光材料的发射和刺激响应性能。本文综述了烷基长度对固态荧光和机械致变色行为的影响，旨在引起人们在有机光电材料的设计、合成和结构-性能研究中对烷基长度效应的进一步关注。
The introduction of alkyl chains to the periphery of the conjugated skeleton of organic chromophores is generally to improve their solubility. However, a number of investigations show that the length of alkyl chains could affect significantly the solid-state molecular packing modes and optical and electronic properties, and thereby alkyl chains could play functional roles in tuning and altering the solid-state aggregation behavior and optoelectronic properties. While there have been a variety of reports on the impact of alkyl chains on organic field-effect transistor and photovoltaic performances, recently increasing interest has been paid to how the alkyl length affects the emission and stimuli responsive properties of organic fluorescent materials. This review focuses on alkyl length effects on solid-state fluorescence and mechanochromic behaviors, and the purpose is to arouse one's further attention to the alkyl-length effect in the design, synthesis and structure–property investigation of organic optoelectronic materials.
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影响因子：
6.4
作者：
Marta Martínez‐Abadía;S. Varghese;R. Giménez;M. Ros
通讯作者：
Marta Martínez‐Abadía;S. Varghese;R. Giménez;M. Ros
DOI：
10.1021/jp202112e
发表时间：
2011-05
期刊：
The journal of physical chemistry. B
影响因子：
--
作者：
Xiqi Zhang;Zhenguo Chi;Jianyong Zhang;Hai-yin Li;Bingjia Xu;Xiaofang Li;Siwei Liu;Yi Zhang
通讯作者：
Xiqi Zhang;Zhenguo Chi;Jianyong Zhang;Hai-yin Li;Bingjia Xu;Xiaofang Li;Siwei Liu;Yi Zhang
影响因子：
3.7
作者：
N. S. S. Kumar-N.-S.-S.-Kumar-2107468207;S. Varghese;N. Rath;Suresh Das
通讯作者：
N. S. S. Kumar-N.-S.-S.-Kumar-2107468207;S. Varghese;N. Rath;Suresh Das
影响因子：
4.9
作者：
W. Liu;Yalong Wang;Mingxia Sun;Deteng Zhang;Meng Zheng;Wenjun Yang
通讯作者：
W. Liu;Yalong Wang;Mingxia Sun;Deteng Zhang;Meng Zheng;Wenjun Yang
DOI：
10.1021/jp053113j
发表时间：
2005-10
期刊：
The journal of physical chemistry. B
影响因子：
--
作者：
Zixing Wang;Hongxia Shao;Jianchuan Ye;Lei Tang;P. Lu
通讯作者：
Zixing Wang;Hongxia Shao;Jianchuan Ye;Lei Tang;P. Lu