First synthesis of the bismole‐containing conjugated polymer

First synthesis of the bismole‐containing conjugated polymer
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DOI：
10.1002/pola.21590
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发表时间：
2006-08
期刊：
Journal of Polymer Science Part A
影响因子：
--
通讯作者：
Y. Morisaki;K. Ohashi;Haining Na;Y. Chujo
Y. Morisaki;K. Ohashi;Haining Na;Y. Chujo
中科院分区：
其他
文献类型：
--
作者：
Y. Morisaki;K. Ohashi;Haining Na;Y. Chujo

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我们通过聚合物反应构建环戊二烯骨架（双摩尔），成功合成了第一个在共轭主链上含有铋原子的共轭聚合物。讨论了所得聚合物的合成过程和表征。这种含有双摩尔的共轭聚合物在溶液中表现出适度的蓝绿色光致发光。 © 2006 Wiley periodicals, Inc. J Polym Sci Part A：Polym Chem 44：4857–4863，2006
We successfully synthesized the first conjugated polymer containing a bismuth atom in the conjugated main chain by incorporating a bismuth atom into the cyclopentadiene framework (bismole), which was constructed by a polymer reaction. A synthetic procedure and characterization of the obtained polymers were discussed. This bismole-containing conjugated polymer exhibited moderate bluish green photoluminescence in solution. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4857–4863, 2006