A donor-acceptor molecular dyad showing multiple electronic energy-transfer processes in crystalline and amorphous states

A donor-acceptor molecular dyad showing multiple electronic energy-transfer processes in crystalline and amorphous states
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在晶体态和非晶态下显示多种电子能量转移过程的供体-受体分子二元体

DOI:
10.1021/ja800387d
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发表时间:
2008-06-11
影响因子:
15
通讯作者:
Clegg, William
Clegg, William
中科院分区:
化学1区
文献类型:
--
作者:
Benniston, Andrew C.;Copley, Graeme;Clegg, William

文献摘要

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单线态-单线态、单线态-三线态和三线态-三线态能量转移发生在包含二吡咯亚甲基硼和低聚噻吩亚基的分子二联体的单晶和无定形固态溶液内。晶体和升华的薄膜具有强烈的荧光。
Singlet-singlet, singlet-triplet, and triplet-triplet energy transfer takes place within single crystals and amorphous solid-state solutions of a molecular dyad comprising boron dipyrromethene and oligo-thiophene subunits. The crystal and sublimed thin-films are strongly fluorescent.