The reductive amination of aldehydes and ketones by catalytic use of dibutylchlorotin hydride complex
The reductive amination of aldehydes and ketones by catalytic use of dibutylchlorotin hydride complex
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DOI：
10.1039/b610614e
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发表时间：
2006-10-28
影响因子：
4.9
通讯作者：
Baba, Akio
中科院分区：
文献类型：
--
作者：
Kato, Hirofumi;Shibata, Ikuya;Baba, Akio
直接使用Bu_2SnClH-吡啶N-氧化物作为催化剂，有效地促进了Ph_2SiH_2或PhSiH_3还原胺化醛或酮的反应;该方法具有条件温和和广泛适用于各种羰基和胺（包括脂肪族实例）的优点。
The reductive amination of aldehydes or ketones using Ph2SiH2 or PhSiH3 has been effectively promoted by the direct use of Bu2SnClH-pyridine N-oxide as a catalyst; this method has advantages in terms of its mild conditions and wide application to various carbonyls and amines, including aliphatic examples.