Headgroup orientations of alkyl glycosides at a lipid bilayer interface
Headgroup orientations of alkyl glycosides at a lipid bilayer interface
复制标题
脂质双层界面处烷基糖苷的头基取向
DOI：
--
复制
发表时间：
1992
期刊：
影响因子：
--
通讯作者：
J. Prestegard
中科院分区：
文献类型：
--
作者：
C. Sanders;J. Prestegard
合成了一系列与功能相关的烷基单糖苷类化合物，并利用取向液晶相13C核磁共振波谱的偶极耦合数据研究了它们的头基取向。合成了13个碳标化合物：β-十二烷基半乳糖苷、β-十四基2-脱氧吡喃葡萄糖苷、β-十二基6-脱氧吡喃葡萄糖苷、α-十二烷基-2-脱氧吡喃葡萄糖苷、α-十四基-2-脱氧吡喃葡萄糖苷、α-十二基2-脱氧吡喃葡萄糖苷、α-十二基2，3-二脱氧赤潮红-六-2-烯吡喃糖苷
A series of functionally related alkyl monoglycosides was prepared, and their headgroup orientations were examined using dipolar coupling data from 13 C NMR spectra in oriented liquid crystalline phases. The following 13 C-labeled compounds were synthesized: β-dodecyl galactopyranoside, β-tetradecyl 2-deoxyglucopyranoside, β-dodecyl 6-deoxyglucopyranoside, α-dodecyl glucopyranoside, α-tetradecyl 2-deoxyglucopyranoside, α-dodecyl 2,3-dideoxyglucopyranoside, and α-dodecyl 2,3-dideoxyerythro-hex-2-enopyranoside