Defocused Emission Patterns from Chiral Fluorophores: Application to Chiral Axis Orientation Determination
Defocused Emission Patterns from Chiral Fluorophores: Application to Chiral Axis Orientation Determination
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手性荧光团的散焦发射模式：在手性轴方向测定中的应用
DOI：
10.1021/jz2001024
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发表时间：
2011
影响因子：
5.7
通讯作者：
M. Barnes
中科院分区：
文献类型：
--
作者：
A. Cyphersmith;A. Maksov;R. Hassey;K. McCarthy;M. Barnes
实验离焦荧光发射模式从单手性分子系统相比，半经典模拟作为一种手段，在单分子系统中的手性轴取向的先验确定。使用耦合振荡器模型作为辐射源，我们表明，从手性荧光团的散焦发射模式的基本特征可以恢复，并建议在单分子系统中的手性轴取向确定（在一定限度内）的可行性。
Experimental defocused fluorescence emission patterns from single chiral molecular systems are compared to semiclassical simulations as a means for a priori determination of chiral axis orientation in single-molecule systems. Using a coupled-oscillator model as a radiation source, we show that the basic features of defocused emission patterns from chiral fluorophores can be recovered and suggests the feasibility of chiral axis orientation determination (within some limits) in single-molecule systems.
影响因子：
3.5
作者：
Mattheyses, AL;Axelrod, D
通讯作者：
Axelrod, D