A non-classical hydrogen bond in the molybdenum arene complex [η6-C6H5C6H3(Ph)OH]Mo(PMe3)3:: evidence that hydrogen bonding facilitates oxidative addition of the O-H bond
A non-classical hydrogen bond in the molybdenum arene complex [η6-C6H5C6H3(Ph)OH]Mo(PMe3)3:: evidence that hydrogen bonding facilitates oxidative addition of the O-H bond
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DOI：
10.1039/b208678f
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发表时间：
2002-11-21
影响因子：
4.9
通讯作者：
Parkin, G
中科院分区：
文献类型：
--
作者：
Hascall, T;Baik, MH;Parkin, G
Mo（PMe 3）（6）与2，6-Ph_2C_6H_3OH反应，合成了eta（6）-芳烃配合物[eta（6）-C_6H_5C_6H_3（Ph）OH]Mo（PMe 3）（3）。H-OAr氢键; DFT计算表明，氢键作用促进了O-H键的氧化加成，生成[eta（6），eta（1）-C6 H5 C6 H3（Ph）O]Mo（PMe 3）（2）H.
Mo(PMe3)(6) reacts with 2,6-Ph2C6H3OH to give the eta(6)-arene complex [eta(6)-C6H5C6H3(Ph)OH]Mo(PMe3)(3) which exhibits a non-classical Mo...H-OAr hydrogen bond; DFT calculations indicate that the hydrogen bonding interaction facilitates oxidative addition of the O-H bond to give [eta(6),eta(1)- C6H5C6H3(Ph)O]Mo(PMe3)(2)H.