Determination of the hydrogen site occupation in the α phase of zirconium hydride and in the α and β phases of titanium hydride by inelastic neutron scattering

Determination of the hydrogen site occupation in the α phase of zirconium hydride and in the α and β phases of titanium hydride by inelastic neutron scattering
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DOI:
10.1088/0305-4608/12/1/003
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发表时间:
1982
期刊:
Journal of Physics F: Metal Physics
影响因子:
--
通讯作者:
R. Khoda-bakhsh;D. Ross
R. Khoda-bakhsh;D. Ross
中科院分区:
其他
文献类型:
--
作者:
R. Khoda-bakhsh;D. Ross

文献摘要

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非弹性中子散射测量已被用来确定由氢在α Zr-H和α和β Ti-H占据的网站。在所有情况下,测量的光学峰频率仅与位于四面体位点上的氢一致。氢化物相和固溶体相之间的能量转移的意义进行了讨论。
Inelastic neutron scattering measurements have been used to determine the site occupied by hydrogen in alpha Zr-H and alpha and beta Ti-H. The measured optical peak frequencies were only consistent with hydrogen being located on the tetrahedral sites in all cases. The significance of the energy shift between the hydride phase and the solid-solution phase is discussed.