A Spherical Molecule with a Carbon-Free Ih-C80 Topological Framework

A Spherical Molecule with a Carbon-Free Ih-C80 Topological Framework
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DOI:
10.1002/anie.200900342
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发表时间:
2009-01-01
影响因子:
16.6
通讯作者:
Peresypkina, Eugenia V.
Peresypkina, Eugenia V.
中科院分区:
化学1区
文献类型:
--
作者:
Scheer, Manfred;Schindler, Andrea;Peresypkina, Eugenia V.

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由五磷杂二茂铁和 CuICl 组成的类富勒烯结构单元系统对原碳硼烷的完全封装导致球形超分子 C2B10H12§[{Cp*Fe(η5-P5)}12(CuCl)20] 的形成。这种模板控制聚集的产物代表了具有二十面体对称性的无碳 C80 类似物的第一个例子。
The complete encapsulationofortho‐carborane by a fullerene‐like building‐block system consisting of pentaphosphaferrocene and CuICl leads to the formation of the spherical supermolecule C2B10H12§[{Cp*Fe(η5‐P5)}12(CuCl)20]. This product of template‐controlled aggregation represents the first example of a carbon‐free C80analogue possessing icosahedral symmetry.