A Spherical Molecule with a Carbon-Free Ih-C80 Topological Framework
A Spherical Molecule with a Carbon-Free Ih-C80 Topological Framework
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DOI:
10.1002/anie.200900342
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发表时间:
2009-01-01
影响因子:
16.6
通讯作者:
Peresypkina, Eugenia V.
中科院分区:
文献类型:
--
作者:
Scheer, Manfred;Schindler, Andrea;Peresypkina, Eugenia V.
The complete encapsulationofortho‐carborane by a fullerene‐like building‐block system consisting of pentaphosphaferrocene and CuICl leads to the formation of the spherical supermolecule C2B10H12§[{Cp*Fe(η5‐P5)}12(CuCl)20]. This product of template‐controlled aggregation represents the first example of a carbon‐free C80analogue possessing icosahedral symmetry.