A bonding-reactivity relationship for (carbon dioxide)bis(tricyclohexylphosphine)nickel: a comparative solid-state-solution nuclear magnetic resonance study (phosphorus-31, carbon-13) as a diagnostic tool to determine the mode of bonding of carbon dioxide to a metal center
A bonding-reactivity relationship for (carbon dioxide)bis(tricyclohexylphosphine)nickel: a comparative solid-state-solution nuclear magnetic resonance study (phosphorus-31, carbon-13) as a diagnostic tool to determine the mode of bonding of carbon dioxide to a metal center
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(二氧化碳)双(三环己基膦)镍的键合反应性关系：比较固态溶液核磁共振研究（磷-31、碳-13）作为诊断工具，以确定二氧化碳与镍的键合模式
DOI：
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发表时间：
1992
期刊：
影响因子：
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通讯作者：
I. Tommasi
中科院分区：
文献类型：
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作者：
M. Aresta;R. Gobetto;E. Quaranta;I. Tommasi
本文首次利用变温下固体和溶液中的31P和13C核磁共振谱确定了Ni（PCy3）2（CO2）中CO2成键模式的直接相关性。
31 P and 13 C nuclear magnetic resonance spectra in the solid state and in solution, at variable temperature, have been used for the first time to determine a direct correlation of the modes of bonding of CO 2 in Ni(PCy 3 ) 2 (CO 2 ) in the two states.