KOtBu-Promoted C4 Selective Coupling Reaction of Phenols and [60]Fullerene: One-Pot Synthesis of 4-[60]Fullerephenols under Transition-Metal-Free Conditions
KOtBu-Promoted C4 Selective Coupling Reaction of Phenols and [60]Fullerene: One-Pot Synthesis of 4-[60]Fullerephenols under Transition-Metal-Free Conditions
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DOI：
10.1021/acs.joc.8b00261
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发表时间：
2018-05-18
影响因子：
3.6
通讯作者：
Tian, Yupeng
中科院分区：
文献类型：
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作者：
Li, Fei;Xuan, Jun;Tian, Yupeng
公开了一种（KOBU）-Bu-t-促进的酚类和[60]富勒烯的直接偶联反应。该反应仅发生在酚的C4-位，具有高的区域选择性，并以良好的产率提供了一种有效和廉价的方法来制备各种4-[60]富勒烯酚。产物的电化学性质使该方法具有吸引力和价值。
A (KOBu)-Bu-t-promoted direct coupling reaction of phenols and [60]fullerene was disclosed. The reaction occurs exclusively at the C4-position of phenols with high regioselectivity and provides an efficient and inexpensive manner to various 4-[60]fullerephenols in good yields. The electrochemical properties of the products render the method attractive and valuable.