A combined experimental and computational study of NHC-catalyzed allylation of allenoate with MBH esters: new regiospecific and stereoselective access to 1,5-enyne

A combined experimental and computational study of NHC-catalyzed allylation of allenoate with MBH esters: new regiospecific and stereoselective access to 1,5-enyne
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NHC 催化联烯酸酯与 MBH 酯烯丙基化的综合实验和计算研究:新的区域特异性和立体选择性获得 1,5-烯炔

DOI:
10.1039/d1qo01083b
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发表时间:
2022
影响因子:
5.4
通讯作者:
Changsheng Yao
Changsheng Yao
中科院分区:
化学1区
文献类型:
--
作者:
Fang Sun;Fangfang Lu;Xue Song;Wenchao Wu;Kai Zhang;Chenxia Yu;Tuanjie Li;Donghui Wei;Changsheng Yao

文献摘要

相似文献

nhc催化α-取代的烯丙酸酯与芳醛衍生的MBH碳酸酯的区域特异性烯丙化反应提供了高度功能化的1,5-烯炔。
An NHC-catalyzed regiospecific allylation of α-substituted allenoates with MBH carbonates derived from aryl aldehyde furnished highly functionalized 1,5-enynes.