Electrochemical generation of C602+ and C603+
Electrochemical generation of C602+ and C603+
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DOI：
10.1021/ja0388515
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发表时间：
2003-12-24
影响因子：
15
通讯作者：
Zaopo, A
中科院分区：
文献类型：
--
作者：
Bruno, C;Doubitski, I;Zaopo, A
采用合适的实验条件，包括超干溶剂和具有非常高的抗氧化性和低亲核性的电解质，首次观察到C602+和C603+的循环伏安可逆生成。本研究为这些重要的全碳碳正离子仍然相对未知的性质提供了有价值的信息，并且鉴于它们非常高的反应活性，为富勒烯的功能化提供了新的可能途径。
The adoption of suitable experimental conditions, which comprise ultra-dry solvents and electrolytes with very high oxidation resistance and low nucleophilicity, has allowed observation, for the first time, of the cyclic voltammetric reversible generation of C602+and C603+. The present study adds valuable information on the still relatively unknown properties of these importantall-carboncarbocations and, in view of their very high reactivity, offers new possible routes for fullerene functionalization.