MESO-ALKYNYL PORPHYRINS
MESO-ALKYNYL PORPHYRINS
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DOI：
10.1016/s0040-4039(00)91871-9
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发表时间：
1992-02-18
影响因子：
1.8
通讯作者：
ANDERSON, HL
中科院分区：
文献类型：
--
作者：
ANDERSON, HL
以三甲基硅基丙炔醛为原料合成了含meso-炔基取代基的卟啉。 它们的红移紫外光谱和对亲核试剂的不寻常的反应性表明，卟啉π-系统和三键之间有很好的重叠。
Porphyrins with meso-alkynyl substituents have been synthesised from trimethylsilyl propynal. Their red-shifted UV spectra and unusual reactivity towards nucleophiles indicate that there is good overlap between the porphyrin pi-systems and the triple bonds.