The structure of a copper(I)-schiff base complex [CuN(CH2CH2NCHC6H5)3]+[BPh4]−

The structure of a copper(I)-schiff base complex [CuN(CH2CH2NCHC6H5)3]+[BPh4]−
复制标题

铜(I)-席夫碱配合物的结构 [CuN(CH2CH2NCHC6H5)3]+[BPh4]−

DOI：
10.1016/s0277-5387(00)80283-1
复制
发表时间：
1990
期刊：
Polyhedron
影响因子：
2.6
通讯作者：
Zhenggang Xu
Zhenggang Xu
中科院分区：
化学3区
文献类型：
--
作者：
E. C. Alyea;G. Ferguson;M. Jennings;Zhenggang Xu

文献摘要

被引文献

相似文献

A crystal structure analysis of [CuN(CH2CH2NCHC6H5)3]+[BPh4]−reveals that the complex has approximate three-fold symmetry in the solid state with the copper(I) atom having trigonal-pyramidal geometry. Principal dimensions are CuN (apical) 2.232(2), CuN(equatorial) 2.004, 2.006 and 2.019(2) Å, N(ap)CuN(eq) 83.7–84.6(1)°. The CuH distances to theortho-phenyl hydrogen atoms are too long to be considered agostic. The1H NMR spectrum is consistent with a similar structure for the copper(I) cation complex in solution.