Remarkably improved field emission of TiO2 nanotube arrays by annealing atmosphere engineering

Remarkably improved field emission of TiO2 nanotube arrays by annealing atmosphere engineering
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通过退火气氛工程显着改善 TiO2 纳米管阵列的场发射

DOI:
10.1016/j.materresbull.2015.06.036
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发表时间:
2015-10
影响因子:
5.4
通讯作者:
Jian Wang
Jian Wang
中科院分区:
材料科学2区
文献类型:
--
作者:
Jian-Biao Chen;Xu-Qiang Zhang;Yan Li;Jian Wang

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Highly ordered TiO2nanotube arrays (TNAs) were prepared by anodization, and followed by annealing in the atmospheres of Air, Vacuum, Ar, and H2. The effect of annealing atmosphere on the crystal structure, composition, and electronic properties of TNAs were systematically investigated. Raman and EDS results indicated that the TNAs annealed in anaerobic atmospheres contained more oxygen vacancies, which result in the substantially improved electron transport properties and reduced work function. Moreover, it was found that the FE properties of TNAs were highly dependent on the annealing atmosphere. By engineering the annealing atmosphere, the turn-on field as low as 2.44 V/μm can be obtained from TNAs annealed in H2, which was much lower than the value of 18.23 V/μm from the TNAs annealed in the commonly used atmosphere of Air. Our work suggests an instructive and attractive way to fabricate high performance TNAs field emitters.
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