Novel azo-Metal-Organic Framework Showing a 10-Connected bct Net, Breathing Behavior, and Unique Photoswitching Behavior toward CO2
Novel azo-Metal-Organic Framework Showing a 10-Connected bct Net, Breathing Behavior, and Unique Photoswitching Behavior toward CO2
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DOI：
10.1021/acs.inorgchem.5b02037
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发表时间：
2015-12-21
影响因子：
4.6
通讯作者：
Luo, Feng
中科院分区：
文献类型：
--
作者：
Gong, Le Le;Feng, Xue Feng;Luo, Feng
Herein, we report a robust azo-metal-organic framework (MOF), namely, ECUT-15, which can be described as a 10-connected bct net built on trinudear Co-3 subunits. The activated samples of it perform a somewhat breathing behavior. Most importantly, under UV irradiation, this MOP performs outstanding photoswitching behavior toward CO2, giving great variation in the CO2 capture/release performance, for example, 45% under static conditions and 75% under dynamic measurements, as well as instantaneous release of up to 78%.
