Sonochemistry of quinones in argon-saturated aqueous solutions: enhanced cytochrome c reduction.

Sonochemistry of quinones in argon-saturated aqueous solutions: enhanced cytochrome c reduction.
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氩饱和水溶液中醌的声化学:增强细胞色素 c 还原。

DOI:
10.1021/tx990064r
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发表时间:
1999
期刊:
Chemical research in toxicology.
影响因子:
--
通讯作者:
Alegria,AE
Alegria,AE
中科院分区:
--
文献类型:
--
作者:
Lawson,RC;Ferrer,A;Flores,W;Alegria,AE

文献摘要

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氩饱和的醌水溶液的超声波分解导致铁细胞色素(Cytc)还原的增强。在加入超氧化物歧化酶后,Cytcreduction被部分抑制,从而暗示超氧离子在此还原过程中的作用。醌的疏水性和还原电位都不能完全控制Cytcreduction的增强,尽管注意到疏水性与还原电位的偏好。
Sonolysis of argon-saturated aqueous quinone solutions resulted in an enhancement in ferricytochromec(Cytc) reduction. Upon addition of superoxide dismutase, Cytcreduction was partially inhibited, thus implying a role of superoxide ion in this reduction process. Neither quinone hydrophobicity nor reduction potential exclusively controls the Cytcreduction enhancement, although a preference for hydrophobicity versus reduction potential is noted.