A three-dimensional metal-organic framework with a distorted Kagome related layer showing canted antiferromagnetic behaviour.
A three-dimensional metal-organic framework with a distorted Kagome related layer showing canted antiferromagnetic behaviour.
复制标题
DOI：
10.1039/b715314g
复制
发表时间：
2008-03
影响因子：
4.9
通讯作者：
Partha Mahata;D. Sen;S. Natarajan
中科院分区：
文献类型：
--
作者：
Partha Mahata;D. Sen;S. Natarajan
由两个几何构型不同的六配位Mn（2+）离子形成的三维[Mn（3）{C（6）H（3）（COO）（3）}（2）]包含二维-Mn-O-Mn-畸变的Kagome层，显示出较少的挫和自旋倾斜的长程有序，这可能是由于反对称交换。
Three-dimensional [Mn(3){C(6)H(3)(COO)(3)}(2)] comprising two-dimensional -Mn-O-Mn- distorted Kagome layers, formed by two geometrically different hexa-coordinated Mn(2+) ions, show less frustration and spin canted long range ordering possibly due to antisymmetric exchange.