Effects of pressure on PbWO4-III

Effects of pressure on PbWO4-III
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压力对 PbWO4-III 的影响

DOI:
10.1007/s00269-013-0575-7
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发表时间:
2013-02
影响因子:
1.4
通讯作者:
Xu, Jian
Xu, Jian
中科院分区:
地球科学4区
文献类型:
--
作者:
Zhou, Wei;Chen, Ming;Zhou, Wenge;Xu, Jian

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In a hydrostatic pressure environment condition and in manual milling, respectively, investigations of PbWO4-III (P21/n) have been performed by X-ray diffraction and Raman scattering techniques. Experiments found that PbWO4-III keeps its monoclinic structure under hydrostatic pressures with the sample’s anisotropic compressibility up to 14.6 GPa, but transforms to PbWO4-I (I41/a) in a grinding process. The stability and variability of PbWO4-III depending on the strain states were also explored by first-principles calculations of elasticity. Calculations show PbWO4-III has an anisotropic compressibility and a ductile nature with increasing pressure up to 15 GPa.
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