C(sp 3 )–H oxidation and chlorination catalysed by a bioinspired pincer iron( iii ) complex
C(sp 3 )–H oxidation and chlorination catalysed by a bioinspired pincer iron( iii ) complex
复制标题
仿生钳铁 ( iii ) 络合物催化 C(sp 3 )–H 氧化和氯化
DOI：
10.1039/d2dt02005j
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发表时间：
2022
影响因子：
4
通讯作者：
Anderson, Stephen N.
中科院分区：
文献类型：
--
作者：
Han, Jian;Tan, Liming;Wan, Yanjun;Li, Gang;Anderson, Stephen N.
开发了一种用于 C(sp3)-H 键氧化和氯化的钳铁 (III) 催化剂。诊断底物顺式十氢化萘的氧化意味着涉及长寿命的碳中心自由基。机理研究表明 Fe-oxo 物种可能负责决定速率的 C-H 激活步骤。该报告扩大了 C-H 官能化非血红素催化剂的范围。
A pincer iron(III) catalyst for the oxidation and chlorination of C(sp3)–H bonds was developed. Oxidation of a diagnostic substrate cis-decalin implies that a long-lived carbon-centred radical is involved. Mechanistic studies suggest that an Fe-oxo species could be responsible for the rate-determining C–H activation step. This report expands the scope of non-heme catalysts for C–H functionalisation.